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Question of the Day
Which of the following is not true for SN
1
reactions?
SN1 reaction is a two-step reaction, step one is the leaving group leaves, and the second step is the substrate forms a carbocation intermediate. Formation of carbocation intermediate is the rate determining step. Since for the formation of stable intermediate carbocation, highly polar solvent is required. The bulky substituents prevent the nucleophiles from approaching the carbon, which is attached directly to the halogen. SN
2
is also more favorable as the neighboring alkyl groups are electron donating, which helps to stabilize the carbocation. SN1 reaction because the nucleophile is not a part of the rate-determining step.
They occur through a single step concerted reaction
They are favoured by polar solvents
Tertiary alkyl halides generally react through this mechanism
In an SN
2
reaction, the rate determining step is the loss of the leaving group to form the intermediate carbocation.
Concentration of nucleophile does not affect the rate of such reactions
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